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Heres my pick from every film and then a top 5.
DN: Dr No – Nuclear phyisicst, enough said.
FRWL: Kronsteen – Chess grandmaster. IQ is probably off the scale.
GF: Mr Ling – Expert in nuclear fission.
TB: Kotze – Expert in nuclear bombs (and isn’t he Nobel prize winning?)
YOLT: Blofeld – to mastermind such an endeavour he must be pretty bright.
OHMSS: Blofeld – ditto, and now appears to be some sort of chemist into the bargain.
DAF: Dr Metz – Expert in laser technology.
LALD: Probably Bond. Kanaga is just a fairly low level criminal when all said and done.
TMWTGG: Gibson – Solar energy expert.
TSWLM: Dr Beckmann and Professor Markowitz – Created the submarine tracking system.
MR: Drax or Dr Goodhead – Both experts in space tech and to be a fully trained astronaut you have to have a pretty high IQ.
FYEO: Bond or Kristatos I suppose. As Bond wins the day is he the cleverer? But without Columbo Bond would’ve got a knife in the back so….
OP: Jim Fanning probably knows his stuff and went to Oxbridge but Kamal and Orlov are in the mix I guess.
AVTAK: Zorin – On the basis that ‘a few children were born with phenomenal IQs’.
TLD: Bond – the villains are nothing much here.
LTK: Truman Lodge – I reckon hes definitely Ivy League with an MBA which might just mean his family has got money but he does seem to know what hes talking about.
GE: Boris – Computer expert.
TND: Gupta? – His character is some sort of computer whizz so maybe but Carver didn’t get to his position without being a pretty shrewd operator.
TWINE: Dr Arkov – Nuclear expert. Its either him or Dr Christmas Jones!!
DAD: Dr Alvarez (is that his name?) – Pioneering DNA replacement expert. Or Vlad maybe.
CR: Le Chiffre - Maths genius.
QOS: Greene seems reasonably intelligent but Bond outwits him so maybe Bond.
SF: Silva is obviously a computer genius and even though Q is also pretty sharp hes not as quick as Silva is he.
Top 5 (in no particular order. Well I say that, its actually blatantly chronological isnt it?))
Kronsteen
Kotze
Zorin
Le Chiffre
Silva
Also Q really has a claim in most films and I'd certainly imagine his IQ to be higher than Bonds.
Those are very interesting observations. Kronsteen, Zorin and Le Chiffre may well have the 3 best brains. Of all the Bonds, Connery is the one who used his head and deduction powers the most.
Some villains as well, even more...